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Crystal System: Orthorhombic
Status of Occurrence: Confirmed Occurrence
Distribution: Rare
Chemical Composition: Basic copper arsenate
Chemical Formula: Cu2(AsO4)(OH)
Method(s) of Verification: Gwaith-yr-Afon Mine - XRD at the Natural History Museum, London; Dolyhir Quarry - XRD at Manchester Museum and WDS at the Open University (analyses OU P202-P204, P377-P380).

Chemical Group:

Geological Context:

Pale green olivenite coating dark blue azurite within a cavity in limestone from Dolyhir Quarry. Photo by D.I. Green. © D.I. Green.
Crust of acicular olivenite microcrystals from Dolyhir Quarry. Neil Hubbard Collection. Photo D.I. Green, © D.I. Green.
Silky, white, acicular olivenite from Gwaith-yr-Afon Mine in the Central Wales Orefield. Specimen and photo S.A. Rust. © S.A. Rust.
Introduction: olivenite is a supergene mineral that is typically encountered in the oxidized zones of chalcopyrite and arsenopyrite-bearing hydrothermal veins, but can occur in any type of weathered copper-arsenic-bearing primary association. It is usually accompanied by other arsenates such as clinoclase, tyrolite, chalcophyllite, scorodite and pharmacosiderite.
Occurrence in Wales: only discovered in very small quantities in Wales. Olivenite is currently known from two localities. This is in stark contrast to some other UK mining districts - such as Cornwall, where it is widespread and common at some localities. This perhaps reflects the paucity of arsenic/copper-bearing mineral veins with well-developed oxidation zones in Wales.

Key Localities:


  1. Cotterell, T.F., Green, D.I., Hubbard, N., Mason, J.S., Starkey, R.E. and Tindle, A.G., 2011. The Mineralogy of Dolyhir Quarry, Old Radnor, Powys, Wales. UK Journal of Mines and Minerals, 32, 5-61.
  2. Rust, S.A. & Mason, J.S., 1994. An unusual occurrence of arsenate minerals at Gwaith-yr-Afon mine, Dyfed, Wales. Journal of the Russell Society, 5(2), 109-113.